There are a couple of things that seems weird to me.
I do not often see such high VaR and E.Shortfall. I wonder if some computation is wrong.
It is also weird that VaR and E.Shortfall are the same.
You are right. When the values are beyond 100%, it seems weird. It is saying that you can actually lose more than you invested. This usually only happen when you are leveraged, shorting or selling uncovered options etc which StocksCafe do not really support anyway.
I started checking and realized that there are multiple transactions that are highlighted in red. Typically for any columns that are highlighted in red, it indicates potential mistake with input although not always.